大别山菖蒲硬玉石英岩退变质作用过程中岩石地球化学的变异   总被引：2，自引：0，他引：2  

苏文  徐树桐  吴维平  石永红  江来利  刘怡灿 《矿物岩石》2000,20(2):8-13

在大别山菖蒲地区新鲜硬玉石英岩逐步退变为片麻岩的变质作用过程中,其岩相学以及地球化学元素发生了一系列有规律的变化。ＳｉＯ２,ＦｅＯ,微量元素Ｂａ,Ｚｒ,Ｇａ以及稀土元素Ｌａ,Ｃｅ,Ｐｒ,Ｎｄ,Ｓｍ,Ｅｕ逐步升高,而ＴｉＯ２,Ｎａ２Ｏ,Ｆｅ２Ｏ３微量元素Ｒｂ,Ｙ,Ｎｂ以及稀土元素Ｇｄ,Ｔｂ,Ｄｙ,Ｈｏ,Ｅｒ,Ｔｍ,Ｙｂ则逐步降低。这反映了矿物晶内的元素的迁移以及外来流体的参与在一定的程度上制约一岩相  相似文献   

大别山超高压变质带片麻岩锆石中重晶石和硬石膏包裹体及其意义   总被引：5，自引：0，他引：5  

刘景波  叶凯 《岩石学报》2000,16(4):482-484

通过拉曼光谱,识别出大别山超高压变质带片麻岩的锆石中有重晶石和硬石膏包裹体,它们与柯石英共生,由此表明超高压变质过程中存在变质流体。  相似文献   

大别超高压变质过程中流体作用的微量元素效应及其地球化学意义   总被引：3，自引：1，他引：2  

凌文黎  贾望鲁  高山  张本仁 《地球化学》2000,29(6):532-541

对大别地区角闪岩相－麻粒岩相和榴辉岩相岩石进行较系统的地球化学研究,探讨了超高压俯冲变质及折返过程中元素的再分配行为,并就其对变质过程中的部分熔融作用和流体交代作用的指示进行了分析。研究表明,大别榴辉岩原岩在其俯冲过程中发生了部分熔融作用,并在其早期脱水和后期退变质作用过程中与变质流体相之间产生了交换。脱水作用使榴辉岩Ｎｂ／Ｔａ比值升高,但后期的退变质作用使榴辉岩与其寄主围岩间的Ｎｂ／Ｔａ比值相对  相似文献   

前寒武纪变质岩中古断裂构造及其研究意义     

楼法生 《江西地质》2000,14(1):5-9

古断裂是指在变质岩区与谱质岩层变形和南作用同时发生的,在盖层沉积之前形成的断裂,其与断屋有关的断层岩石在后期骏马理新固结成岩。它是前寒武纪变夺内一种重要的构造现象。通过研究,概括总结了古断裂的特点及识别古断裂构造的各种标志,同时探讨了古断理解构造性质。古断裂构造的研究,无乡下对提高前寒武纪地质发展史的认识及对成矿分析和成矿预测具有重要的意义。  相似文献   

Alteration of chromitites from the Voidolakkos and Xerolivado mines,Vourinos ophiolite complex,Greece: implications for deformation‐induced metamorphism     

Argyrios N. Kapsiotis 《Geological Journal》2015,50(6):739-763

Chromitites, associated with upper mantle spinel peridotites from the Voidolakkos and Xerolivado districts, located in the Vourinos ophiolite complex, northwestern continental Greece, were re‐investigated with respect to their structural and textural mode of occurrence, as well as their compositional signatures. They include variably deformed banded and podiform chromitite bodies made up of massive, semi‐massive, nodular, anti‐nodular, schlieren and disseminated chromian spinel. Chromitites have suffered intense shearing that was more severe in all but disseminated textured ore. Deformation has partly produced elongation of chromian spinel nodules and widespread protocataclastic zones within chromitites. The examined deposits are composed of magnesiochromite that shows a quite restricted range of Cr# [Cr/(Cr + Al)] values varying between 0.76 and 0.83, whereas Mg# [Mg/(Mg + Fe²⁺)] ranges from 0.55 to 0.67 accompanied by relatively low content in TiO₂ (<0.15 wt.% on average). Compositional data indicate that these high‐Cr chromitite bodies crystallized from melts of boninitic affinities that have been compositionally modified after reaction with depleted harzburgite, followed by interaction with relatively undifferentiated low SiO₂ melts within an intertwined system of dunite channels in the mantle wedge below the fore‐arc region of a supra‐subduction zone (SSZ). Magnesiochromite displays limited textural modification, being scarcely transformed to an opaque spinel phase along grain boundaries and fracture walls. The opaque spinel phase is characterized by elevated Cr# (0.76–0.97), relatively low Mg# (0.33–0.63) and low Fe³⁺# (≤0.14) and corresponds to ferrian chromite. Microscopic studies revealed that ferrian chromite is paragenetically associated with clinochlore even in unaltered chromitite specimens and the degree of serpentinization does not correlate with the frequency and abundance of alteration effects on magnesiochromite. Therefore, it is supported that regional metamorphism prior to serpentinization was responsible for the formation of the ferrian chromite–clinochlore association. In addition, magnesiochromite alteration was systematically recorded only in variably sheared chromitites displaying protocataclastic brecciation, thus it can be claimed that metamorphism was mainly governed by deformation mechanisms, which took place during the transition from ductile to semi‐brittle conditions. Ferrian chromite can be locally erratically enriched in MnO and ZnO, which is attributed to a Mn‐ and Zn‐bearing, slightly acid post‐magmatic fluid that invaded the chromitites across weakness zones. Overall, the data suggest that after magnesiochromite equilibration with the intergranular olivine, both phases were partly replaced by ferrian chromite and clinochlore, respectively, during a brief, fluid assisted episode of retrogade metamorphism that took place within a temperature interval between 700 and 300 °C, before ocean‐floor alteration. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

山东栖霞石榴子石矿床特征及其成因探讨     

马祥县  杨斌  罗文强  唐璐璐 《山东地质》2014,(12):17-19

栖霞石榴子石矿床位于华北板块胶辽隆起区南部栖霞马连庄断凸构造单元。该矿床属片岩型石榴子石矿床。含矿层位为古元古代荆山群禄格庄组安吉村片岩段。矿层一般长400～3450 m,平均1250 m。斜深15．3～306．0 m。厚度2．00～23．34 m,平均8．34 m,厚度变化系数50％左右。吕梁运动使荆山群发生了强烈的区域变质作用,变质程度达到高角闪岩相,生成了应力矿物石榴子石和矽线石,石榴子石富集成矿。  相似文献   

Mineralogical and microfabric characteristics of magnetite in the Wuyang Precambrian BIFs,southern North China Craton: Implications for genesis and depositional processes of the associated BIFs     

《Journal of Asian Earth Sciences》2014

Precambrian Banded Iron Formations (BIFs) are widely distributed in the North China Craton (NCC). Among them, the Wuyang BIFs located in the southern margin of NCC occur in the Late Archaean Tieshanmiao Formation and can be subdivided in two different sub-types: (i) quartz–magnetite BIFs (QMB), consisting of magnetite, fine-microcrystalline quartz and minor calcite and (ii) pyroxene–magnetite BIFs (PMB), composed of pyroxene, fine-microcrystalline quartz and subordinate feldspars. Both sub-types display apparent discrepancies in terms of petrography and mineral composition.As shown in Electron BackScattered Diffraction (EBSD) images and micrographs, magnetite grains from the QMB range in size from tens up to hundreds of μm, whereas magnetite crystals from the PMB can be up to a few tens of μm across. The X-ray diffraction (XRD) structural data indicate that magnetite from both BIF sub-types is equiaxed (cubic) and was generated by sedimentary metamorphic processes. The cell parameters of magnetite in the QMB are a = b = c = 8.396 Å and Z = 8, which deviate slightly from these of magnetite in the PMB: a = b = c = 8.394 Å and Z = 8. The analytical results of Raman spectroscopy analysis revealed micro-structural signatures of both magnetite (Raman shifts near 552 cm⁻¹ and 673 cm⁻¹) and hematite (Raman shifts near 227 cm⁻¹, 295 cm⁻¹ and 413 cm⁻¹). In magnetite from both QMB and PMB, the crystallinity degree is similar for magnetite micro-structures but varies significantly for hematite micro-structures. Oxygen fugacity (fO₂) conditions fluctuated during the recrystallization of magnetite in the QMB, whereas no evident variation of fO₂ occurred during the formation of magnetite in the PMB. Analytical results of laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) show that the Si, Al and Mg abundances are higher in magnetite from the QMB, whereas the Ti and Mn contents are more elevated in magnetite from the PMB. Magnetite composition also denotes that both BIF sub-types are sedimentary-metamorphic origin, whereas the deposition of PMB was also affected by volcanic activities. Overall data indicate that the differences in the depositional environment of each BIF sub-type are due to the involvement of volcanic eruption processes in the genesis of the PMB. Thus, this paper indicated that the QMB was deposited by chemical deposition at the long-term interval of volcanic eruptions, and the PMB were the product of chemical deposition affected by the volcanic eruption.  相似文献   

煤的变形产气机理探讨     

侯泉林  雒毅  韩雨贞  李小诗 《地质通报》2014,33(5):715-722

对煤在不同变形机制作用下的化学结构变化与产气等方面的研究成果进行了调研分析,对比总结了国内外有关煤的高温高压实验,提出了一些新的认识和研究方向。①研究表明,不同的变形作用,如脆性变形和韧性变形对煤分子的结构演化趋势和影响机理明显不同;②在煤的高温高压实验方面,许多实验过程都发现了气体的产生,但因实验设计温度过高,超过实验煤的热解甚至裂解温度,因此造成对产气机理的多解性,即气体是煤热解甚至高温裂解产生的,还是由于煤发生变形作用产生的,或者两者均有贡献。利用次高温高压实验探讨变形作用能否促使气体的产生是可行的。综合前人的研究成果认为,煤在构造应力作用下发生变形时能够产生气体,这可能是超量煤层气的来源之一。同时,产出的超量煤层气的赋存状态可能并非仅仅是传统观念的物理吸附,而可能是以低键能的化学键形式存在于煤体结构中。  相似文献   

呼鲁斯太矿区煤层瓦斯分布规律及其控制因素探讨     

田俊伟 《中国煤炭地质》2014,(9):27-30

根据煤矿井下煤层瓦斯参数测定结果,以瓦斯地质理论为基础,分析了呼鲁斯太矿区瓦斯分布规律及其控制因素。结果表明:矿区煤层瓦斯区域分布具有不均衡性,以F2-2和F22断层为界将矿区划分为北部、中部、南部三个区域,中部煤层瓦斯压力、瓦斯含量最高,北部次之,南部最低;煤变质程度较高和围岩封闭性较好是矿区瓦斯富集的根本条件,而构造复杂程度的不同、构造线方向的改变是瓦斯分布不均的主控因素。矿区中部为北北东向构造向东西向构造转折区,应力集中,且顶板为泥岩,煤变质程度较高,形成较好的瓦斯生储条件;南部北北东向推覆构造较为强烈,使煤层沿倾向切割,断层连通地表,造成瓦斯大量逸散。  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987114000449     

Oleg G.Safonov  Leonid Y.Aranovich 《地学前缘(英文版)》2014,5(5):711-727

We review petrologic observations of reaction textures from high-grade rocks that suggest the passage of fluids with variable alkali activities. Development of these reaction textures is accompanied by regular compositional variations in plagioclase, pyroxenes, biotite, amphibole and garnet. The textures are interpreted in terms of exchange and net-transfer reactions controlled by the K and Na activities in the fluids. On the regional scale, these reactions operate in granitized, charnockitized, syenitized etc. shear zones within high-grade complexes. Thermodynamic calculations in simple chemical systems show that changes in mineral assemblages, including the transition from the hydrous to the anhydrous ones, may occur at constant pressure and temperature due only to variations in the H2O and the alkali activities. A simple procedure for estimating the activity of the two major alkali oxides, K2O and Na2O, is imple- mented in the TWQ software. Examples of calculations are presented for well-documented dehydration zones from South Africa, southern India, and Sri Lanka. The calculations have revealed two end-member regimes of alkalis during specific metamorphic processes： rock buffered, which is characteristic for the precursor rocks containing two feldspars, and fluid-buffered for the precursor rocks without K-feldspar. The observed reaction textures and the results of thermodynamic modeling are compared with the results of available experimental studies on the interaction of the alkali chloride and carbonate-bearing fluids with metamorphic rocks at mid-crustal conditions. The experiments show the complex effect of alkali activities in the fluid phase on the mineral assemblages. Both thermodynamic calculations and experiments closely reproduce paragenetic relations theoretically predicted by D.S. Korzhinskii in the 1940s.  相似文献